About this material
Bergamal TOCO by IFF is a refined perfumery ingredient designed to elevate and sculpt the radiance of citrus compositions with exceptional finesse.
Crafted for precision and elegance, it is particularly effective in enhancing the tonality of bergamot and other citrus notes, bringing clarity, brightness, and a sophisticated naturalness to fragrance accords.
Expert perfumers also value its versatility in transforming orange oils—subtly manipulating their profile to create the nuanced illusion of true bergamot.
Stabilised with tocopherol, Bergamal TOCO offers both performance and longevity, ensuring consistency within even the most intricate formulations.
Its olfactive profile opens with a fresh, lemon-lifted bergamot character, seamlessly unfolding into smooth verbena facets and gently settling into dry orange undertones.
This harmonious balance allows it to enhance and illuminate citrus bouquets, adding lift, diffusion, and refinement to complex compositions.
An essential tool for modern fragrance creation, Bergamal TOCO embodies both technical mastery and sensory elegance—bringing a luminous, polished citrus signature to fine perfumery.
Scent character
Highlights from the material’s listed odour profile.
Note position
Top note
Material character
A closer lookOdour strength
(recommend smelling in a 10% solution or less)
Listed qualitative strength
Tenacity / substantivity
6 hour(s)
at 100%
Listed reference conditions
Fragrance development
Top note
Illustrative note development · no measured evaporation data
Molecular identity

C11H18O
CAS-linked compound reference — 3,7-Dimethyl-2-methylene-6-octenal, (+-)-
This compound record is linked to the explicitly recorded CAS number. It is not supplier confirmation of the supplied grade, purity, stereochemistry, isomer proportions or complete composition.
- Reference molecular weight
- 166.26 g/mol
- Reference IUPAC name
- 3,7-dimethyl-2-methylideneoct-6-enal
More compound properties
Computed and structural reference properties for the named compound. These are not measured supplier specifications or properties of a complete dilution, mixture or batch.
- XLogP (computed)
- 3.4
- Exact mass (Da)
- 166.135765193
- Monoisotopic mass (Da)
- 166.135765193
- Topological polar surface area (Ų)
- 17.1
- Complexity
- 185
- Formal charge
- 0
- Hydrogen bond donors
- 0
- Hydrogen bond acceptors
- 1
- Rotatable bonds
- 5
- Heavy atoms
- 12
- Isotope atoms
- 0
- Atom stereocentres
- 1
- Bond stereocentres
- 0
- Covalent units
- 1
- SMILES
- CC(CCC=C(C)C)C(=C)C=O
- InChI
- InChI=1S/C11H18O/c1-9(2)6-5-7-10(3)11(4)8-12/h6,8,10H,4-5,7H2,1-3H3
- InChIKey
- FAGYGFPZNTYLAO-UHFFFAOYSA-N
Reference data checked 2026-10-27.
CAS 22418-66-2 · reference checked 2026-10-27.
Fragrance allergen reference
Generic regulatory reference only. This is not a supplier allergen declaration, measured composition, allergen-free claim or finished-product labelling assessment.
Raw-material reference based on recorded CAS numbers. A CAS match identifies a reference entry; it does not verify the supplied grade, composition, purity or finished-product compliance. Naturals, bases and mixtures require composition review.
European Union / Northern Ireland
No direct listed-entry CAS match in this jurisdiction’s held reference set. This does not mean the material is allergen-free. Constituents, grouped entries and natural-material composition may require further review.
Finished-cosmetic declaration thresholds: greater than 0.001% leave-on; greater than 0.01% rinse-off. Apply the current target-market rules to the actual complete formulation; no concentration is inferred here.
Commission Regulation (EU) 2023/1545 · Regulation (EU) 2023/1545 with 11 November 2025 corrigendum; checked 2026-10-26.
Held EU transition dates: placing noncompliant products on the market until 2026-07-31; making them available until 2028-07-31. Check applicability and current law for the intended market. 2025 corrigendum.
Great Britain
No direct listed-entry CAS match in this jurisdiction’s held reference set. This does not mean the material is allergen-free. Constituents, grouped entries and natural-material composition may require further review.
Finished-cosmetic declaration thresholds: greater than 0.001% leave-on; greater than 0.01% rinse-off. Apply the current target-market rules to the actual complete formulation; no concentration is inferred here.
Regulation (EC) No 1223/2009, Annex III (Great Britain) · legislation.gov.uk current text checked 2026-10-26.
Current supplier composition or allergen declarations are required to assess naturals, bases, mixtures and actual concentrations. Reference data checked 2026-10-26; bundle 2026-10-27. Supplementary private documents remain separate.
Product specification
| CAS number | 22418-66-2 |
|---|---|
| Odour description (decreasing) | Refreshing, Aldehydic, Lemon, Citronella, Verbena note with definite Bergamot and dry Orange moieties |
| Odour strength | Medium (recommend smelling in a 10% solution or less) |
| Perfumery use | Effective from the smallest traces, through to 10%Listed perfumery guidance; this is not an IFRA limit. |
| Substantivity | 6 hour(s) at 100% |
| Solvent | None |
| Physical state | Liquid |
| Synonyms | Alpha-Methylene Citronellal |
Safety & handling
Signal word: Warning
Hazard statements:
- H316 Causes mild skin irritation.
Precautionary statements:
- P332+P313 If skin irritation occurs: Get medical advice/attention.
Professional/Industrial use only.
Datasheets & customer documents
Available documents are attached to eligible completed orders in your account.
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Supplementary documents are supplied only where explicitly listed and available. Check documentation information
Purchased as a guest? Follow the SDS request guidance in our Documentation Supply Policy and provide proof of purchase.
Documentation Supply PolicyIFRA formulation guide
Generic reference only — not an IFRA certificate, compliance decision or use recommendation. The Responsible Person and qualified safety assessor must assess the actual finished formula using current applicable IFRA Standards, supplementary documentation where available and the CPSR.
Raw-material reference based on recorded CAS numbers. A CAS match identifies a reference entry; it does not verify the supplied grade, composition, purity or finished-product compliance. Naturals, bases and mixtures require composition review.
Source: 51st Amendment overview, held source checked 2026-10-21. Bundle 2026-10-27. Individual Standards prevail over the overview.
No direct IFRA overview entry matched the recorded CAS in this held dataset. This does not mean unrestricted use, absence of relevant Standards or compliance. Constituent restrictions may still apply.
IFRA source overview · Individual IFRA Standards and supplementary documentation
Supplier certificates and private documents are separate evidence. Their availability does not determine whether this generic guide is shown. This is a dated local reference, not a live regulatory feed.
Creative ideas to explore
Creative directions, not tested formulas.Polished petals
With rose and soft floral notesExplore an aldehydic floral silhouette around a simple rose accord. Compare the opening and later impression with an unchanged floral reference; decide whether the effect feels airy, waxy or abstract before adding further complexity.
Citrus in white
With bergamot and a musk directionBuild a study around citrus brightness and a restrained musk backdrop. Let the aldehydic material be the changing variable, then note whether it supports the peel impression or takes the sketch towards a more abstract clean accord.
A softer frame
With sandalwood and powdery notesSet the listed aldehydic character against a soft wood or powder direction. Compare the balance through the evaluation rather than judging only the first impression, and keep any successful version simple enough to understand what changed.






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