About this material
Trans-2-Hexenal is an incisive green aldehyde with the vivid freshness of snapped leaves, tart apple skin and citrus peel.
Its energy is immediate, bringing a composition into focus with a crisp, almost electric line.
The material is more than a cut-grass effect. A spicy-fruity undertone allows it to animate apple, strawberry and tropical ideas, while its aldehydic sharpness can lend modernity to florals, colognes and green woods.
It captures the moment greenery is disturbed: a leaf torn open, a stem snapped or the skin of an unripe fruit cut by a blade. This vivid immediacy can make an accord feel startlingly present and alive.
Odour profile
The odour is strongly green and leafy, with sharp citrus, green-apple and spicy nuances.
It is bright, penetrating and highly recognisable, becoming more naturalistic and fruit-like as it is carefully diluted.
The opening is piercing and energetic, dominated by leaf sap, tart peel and green apple skin.
Its aldehydic character gives the note a clean, linear projection that commands attention even at very low levels.
With careful dilution, fruitier and more aromatic details emerge.
Citrus, spice and crisp orchard-fruit nuances soften the raw greenery, revealing a versatile material capable of both naturalistic and highly stylised effects.
Using Trans-2-Hexenal in perfumery
Trans-2-Hexenal can create freshly cut stems, leaf sap, fruit skin and crisp green top notes.
It is useful in apple, pear, strawberry, citrus, violet-leaf and botanical accords, and can add tension to soft florals or dry woody structures.
In botanical compositions, it can provide the flash of sap that makes leaves, stems and cut grass feel freshly rendered.
In apple, pear, strawberry and citrus accords, it brings tartness, peel and a convincing sense of unripened texture.
It can also introduce tension to rose, jasmine, violet-leaf and dry-wood structures, preventing softer materials from feeling static.
Because its impact is immediate, gradual dosing allows the desired green detail to remain precise and luxurious.
Creative pairings
Explore Trans-2-Hexenal with galbanum, violet leaf, cis-3-hexenol, bergamot, grapefruit, apple, pear, strawberry, basil, jasmine, cedarwood and vetiver.
Blend with cis-3-hexenol for a fuller green-leaf effect: the trans isomer brings fruity notes, while the cis isomer delivers pure green character.
Precision is essential: a trace can feel remarkably alive, while excess can dominate the entire opening.
For a vivid garden impression, combine it with galbanum, violet leaf, basil, jasmine and wet-earth materials such as geosmin.
For a crisp fruit direction, explore bergamot, grapefruit, apple, pear and strawberry, grounded by cedarwood, vetiver or transparent musk.
Scent character
Highlights from the material’s listed odour profile.
Note position
Top note
Material character
A closer lookOdour strength
(recommend smelling in a 1% solution or less)
Listed qualitative strength
Tenacity / substantivity
< 8 hour(s) at 10%
Listed reference conditions
Fragrance development
Top note
Illustrative note development · no measured evaporation data
Molecular identity
C6H10O
- Molecular weight
- 98.14 g/mol
- IUPAC name
- (E)-hex-2-enal
More compound properties
Computed and structural reference properties for the named compound. These are not measured supplier specifications or properties of a complete dilution, mixture or batch.
- XLogP (computed)
- 1.5
- Exact mass (Da)
- 98.073164938
- Monoisotopic mass (Da)
- 98.073164938
- Topological polar surface area (Ų)
- 17.1
- Complexity
- 64
- Formal charge
- 0
- Hydrogen bond donors
- 0
- Hydrogen bond acceptors
- 1
- Rotatable bonds
- 3
- Heavy atoms
- 7
- Isotope atoms
- 0
- Atom stereocentres
- 0
- Bond stereocentres
- 1
- Covalent units
- 1
- SMILES
- CCC/C=C/C=O
- InChI
- InChI=1S/C6H10O/c1-2-3-4-5-6-7/h4-6H,2-3H2,1H3/b5-4+
- InChIKey
- MBDOYVRWFFCFHM-SNAWJCMRSA-N
Reference data checked 2026-10-27.
This molecular reference matches the catalogue’s recorded CAS and formula. It does not confirm the supplied grade, purity, stereochemistry, isomer proportions, composition, impurities or unlisted constituents.
Fragrance allergen reference
Generic regulatory reference only. This is not a supplier allergen declaration, measured composition, allergen-free claim or finished-product labelling assessment.
Raw-material reference based on recorded CAS numbers. A CAS match identifies a reference entry; it does not verify the supplied grade, composition, purity or finished-product compliance. Naturals, bases and mixtures require composition review.
European Union / Northern Ireland
No direct listed-entry CAS match in this jurisdiction’s held reference set. This does not mean the material is allergen-free. Constituents, grouped entries and natural-material composition may require further review.
Finished-cosmetic declaration thresholds: greater than 0.001% leave-on; greater than 0.01% rinse-off. Apply the current target-market rules to the actual complete formulation; no concentration is inferred here.
Commission Regulation (EU) 2023/1545 · Regulation (EU) 2023/1545 with 11 November 2025 corrigendum; checked 2026-10-26.
Held EU transition dates: placing noncompliant products on the market until 2026-07-31; making them available until 2028-07-31. Check applicability and current law for the intended market. 2025 corrigendum.
Great Britain
No direct listed-entry CAS match in this jurisdiction’s held reference set. This does not mean the material is allergen-free. Constituents, grouped entries and natural-material composition may require further review.
Finished-cosmetic declaration thresholds: greater than 0.001% leave-on; greater than 0.01% rinse-off. Apply the current target-market rules to the actual complete formulation; no concentration is inferred here.
Regulation (EC) No 1223/2009, Annex III (Great Britain) · legislation.gov.uk current text checked 2026-10-26.
Current supplier composition or allergen declarations are required to assess naturals, bases, mixtures and actual concentrations. Reference data checked 2026-10-26; bundle 2026-10-27. Supplementary private documents remain separate.
Product specification
| CAS number | 6728-26-3 |
|---|---|
| Odour description (decreasing) | Green, Leafy, Fruity, Citrus, Spicy, Sharp |
| Odour strength | High (recommend smelling in a 1% solution or less) |
| Perfumery use | Precise leafy-green accents, crisp fruit-peel details and botanical top-note effects.Listed perfumery guidance; this is not an IFRA limit. |
| Typical use percentage | Effective from the smallest traces, through to 0.1% |
| Substantivity | < 8 hour(s) at 10% |
| Solvent | None |
| Flash point | 43 °C |
| Physical state | Liquid |
| Physical form | Colourless to pale yellow, clear mobile liquid |
| Synonyms | trans-2-Hexenal; (E)-Hex-2-enal; Leaf Aldehyde |
| Molecular formula | C₆H₁₀O |
| Molecular weight | 98.14 g/mol |
| Supplier IFRA information | Catalogue copy mentions IFRA information, but no reviewed supplier-document record is available in this profile. No certificate, use limit or compliance status is confirmed. |
Safety & handling
Signal word: Danger
Hazard statements
- H226 Flammable liquid and vapour.
- H302 Harmful if swallowed.
- H311 Toxic in contact with skin.
- H317 May cause an allergic skin reaction.
- H411 Toxic to aquatic life with long lasting effects.
Precautionary statements
- P210 Keep away from heat, sparks, open flames and hot surfaces. – No smoking.
- P233 Keep container tightly closed.
- P240 Ground/bond container and receiving equipment.
- P241 Use explosion-proof electrical, ventilating and lighting equipment.
- P242 Use only non-sparking tools.
- P243 Take precautionary measures against static discharge.
- P261 Avoid breathing vapour or dust.
- P264 Wash hands and other contacted skin thoroughly after handling.
- P270 Do no eat, drink or smoke when using this product.
- P272 Contaminated work clothing should not be allowed out of the workplace.
- P273 Avoid release to the environment.
- P280 Wear protective gloves/eye protection/face protection.
- P301/312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
- P303/361/353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
- P312 Call a POISON CENTER or doctor/physician if you feel unwell.
- P330 Rinse mouth.
- P333/313 If skin irritation or rash occurs: Get medical advice/attention.
- P363 Wash contaminated clothing before reuse.
- P370/378 In case of fire: Use for extinction: Foam, Dry chemical, Carbon dioxide.
- P391 Collect spillage.
- P403/235 Store in a well-ventilated place. Keep cool.
- P405 Store locked up.
- P501 Dispose of contents/container to: approved disposal site.
Important: For professional formulation use. Review the Safety Data Sheet before handling, storage or use.
Datasheets & customer documents
Available documents are attached to eligible completed orders in your account.
Sign in to view your ordersMy account → Orders
Supplementary documents are supplied only where explicitly listed and available. Check documentation information
Purchased as a guest? Follow the SDS request guidance in our Documentation Supply Policy and provide proof of purchase.
Documentation Supply PolicyIFRA formulation guide
Generic reference only — not an IFRA certificate, compliance decision or use recommendation. The Responsible Person and qualified safety assessor must assess the actual finished formula using current applicable IFRA Standards, supplementary documentation where available and the CPSR.
Raw-material reference based on recorded CAS numbers. A CAS match identifies a reference entry; it does not verify the supplied grade, composition, purity or finished-product compliance. Naturals, bases and mixtures require composition review.
Source: 51st Amendment overview, held source checked 2026-10-21. Bundle 2026-10-27. Individual Standards prevail over the overview.
2-Hexenal
RESTRICTION · CAS 16635-54-4, 505-57-7, 6728-26-3
Category 4 — fine fragrance: 0.0077% in the finished consumer product
All applicable specification, purity and other Standard conditions must also be met.
All IFRA categories and Standard conditions
| Category 1 | 0.0014% in the finished consumer product |
|---|---|
| Category 2 | 0.00041% in the finished consumer product |
| Category 3 | 0.0083% in the finished consumer product |
| Category 4 | 0.0077% in the finished consumer product |
| Category 5A | 0.0020% in the finished consumer product |
| Category 5B | 0.0020% in the finished consumer product |
| Category 5C | 0.0020% in the finished consumer product |
| Category 5D | 0.00067% in the finished consumer product |
| Category 6 | 0.0045% in the finished consumer product |
| Category 7A | 0.016% in the finished consumer product |
| Category 7B | 0.016% in the finished consumer product |
| Category 8 | 0.00067% in the finished consumer product |
| Category 9 | 0.015% in the finished consumer product |
| Category 10A | 0.054% in the finished consumer product |
| Category 10B | 0.054% in the finished consumer product |
| Category 11A | 0.00067% in the finished consumer product |
| Category 11B | 0.00067% in the finished consumer product |
| Category 12 | No numeric restriction in this overview cell; review the full Standard and other applicable requirements. |
CAS numbers (comment): The scope of this Standard includes, but is not limited to the CAS number(s) indicated above; any other CAS number(s) used to identify this fragrance ingredient should be considered in scope as well.
Contributions from other sources: See Annex
Flavor use consideration: Due to the possible ingestion of small amounts of fragrance ingredients from their use in products in Categories 1 and 6, materials must not only comply with IFRA Standards but must also be recognized as safe as a flavoring ingredient as defined by the IOFI Code of Practice (www.iofi.org). For more details see chapter 1 of the Guidance for the use of IFRA Standards.
IFRA Standard type: RESTRICTION
Intrinsic property driving the risk management measure: DERMAL SENSITIZATION AND SYSTEMIC TOXICITY
Amendment revised: 51
Existing creations deadline: October 30, 2025
New creations deadline: March 30, 2024
IFRA source overview · Individual IFRA Standards and supplementary documentation
Supplier certificates and private documents are separate evidence. Their availability does not determine whether this generic guide is shown. This is a dated local reference, not a live regulatory feed.
Creative ideas to explore
Creative directions, not tested formulas.Leaf and blossom
With rose and garden floralsExplore a green floral sketch around a clear flower reference. Compare the leafy accent with the flower alone and decide whether the scene suggests a cut stem, a growing garden or a greener abstraction you want to develop.
Peel and leaf
With bergamot and herbal directionsUse citrus as a bright setting for the green material, then try an herbal alternative as a separate variation. Keeping those contrasts apart makes it easier to choose between a peel-focused idea and a leafy cologne.
A shaded wood
With transparent woods and soft muskSketch a green wood direction with a restrained backdrop. Follow the leafy character as the study develops, comparing a wood-only reference to decide whether the scene suggests fresh branches, shaded timber or a softer woodland impression.









Reviews
There are no reviews yet