Coumarin D
Sweet, Hay, Tonka, New-mown-hay
Supplied as 10% in DPG.
About this material
Coumarin is a crystallised solid in its pure form. Here we provide a pre-dissolved solution in DPG for your convenience. We do however have the pure crystal form available here if you prefer to work with the pure form of this material.
Coumarin possesses the delicate characteristic sweet odour of Tonka absolute in which it makes up the majority constituent and is probably best known for being the first synthetic material to be used in the art of perfumery.
Extensively used in perfumery to support herbaceous odours, Lavender, Rosemary, Oakmoss, Citrus oils and as a fixative in numerous types of fragrances.
Scent character
Highlights from the material’s listed odour profile.
Note position
Base note
Material character
A closer lookOdour strength
, recommend smelling in a 10% solution or less
Listed qualitative strength
Tenacity / substantivity
> 364 hour(s) at 10% in DPG
Listed reference conditions
Supplied strength is 10% in DPG.
Fragrance development
Base note
Illustrative note development · no measured evaporation data
Molecular identity
C9H6O2
CAS-linked compound reference — Coumarin
This compound record is linked to the explicitly recorded CAS number. It is not supplier confirmation of the supplied grade, purity, stereochemistry, isomer proportions or complete composition.
Named active material only. These properties do not describe the complete supplied dilution or carrier.
- Reference molecular weight
- 146.14 g/mol
- Reference IUPAC name
- chromen-2-one
More compound properties
Computed and structural reference properties for the named compound. These are not measured supplier specifications or properties of a complete dilution, mixture or batch.
- XLogP (computed)
- 1.4
- Exact mass (Da)
- 146.036779430
- Monoisotopic mass (Da)
- 146.036779430
- Topological polar surface area (Ų)
- 26.3
- Complexity
- 196
- Formal charge
- 0
- Hydrogen bond donors
- 0
- Hydrogen bond acceptors
- 2
- Rotatable bonds
- 0
- Heavy atoms
- 11
- Isotope atoms
- 0
- Atom stereocentres
- 0
- Bond stereocentres
- 0
- Covalent units
- 1
- SMILES
- C1=CC=C2C(=C1)C=CC(=O)O2
- InChI
- InChI=1S/C9H6O2/c10-9-6-5-7-3-1-2-4-8(7)11-9/h1-6H
- InChIKey
- ZYGHJZDHTFUPRJ-UHFFFAOYSA-N
Reference data checked 2026-10-27.
CAS 91-64-5 · reference checked 2026-10-27.
Fragrance allergen reference
Generic regulatory reference only. This is not a supplier allergen declaration, measured composition, allergen-free claim or finished-product labelling assessment.
Raw undiluted material reference. These data refer to the named active material, not the complete supplied dilution. A raw-material IFRA ceiling is not a use level for this diluted product. The assessor must account for the actual concentration, carrier and all other formula contributions.
European Union / Northern Ireland
- Coumarin — Annex III entry 77; single-substance reference. Recorded CAS match only; composition and scope require assessment.
Finished-cosmetic declaration thresholds: greater than 0.001% leave-on; greater than 0.01% rinse-off. Apply the current target-market rules to the actual complete formulation; no concentration is inferred here.
Commission Regulation (EU) 2023/1545 · Regulation (EU) 2023/1545 with 11 November 2025 corrigendum; checked 2026-10-26.
Held EU transition dates: placing noncompliant products on the market until 2026-07-31; making them available until 2028-07-31. Check applicability and current law for the intended market. 2025 corrigendum.
Great Britain
- Coumarin — Annex III entry 77; single-substance reference. Recorded CAS match only; composition and scope require assessment.
Finished-cosmetic declaration thresholds: greater than 0.001% leave-on; greater than 0.01% rinse-off. Apply the current target-market rules to the actual complete formulation; no concentration is inferred here.
Regulation (EC) No 1223/2009, Annex III (Great Britain) · legislation.gov.uk current text checked 2026-10-26.
Current supplier composition or allergen declarations are required to assess naturals, bases, mixtures and actual concentrations. Reference data checked 2026-10-26; bundle 2026-10-27. Supplementary private documents remain separate.
Product specification
| CAS number | 91-64-5 |
|---|---|
| Odour description (decreasing) | Sweet, Hay, Tonka, New-mown-hay |
| Odour strength | High, recommend smelling in a 10% solution or less |
| Perfumery use | Effective from the smallest traces, through to 1%Listed perfumery guidance; this is not an IFRA limit. |
| Substantivity | > 364 hour(s) at 10% in DPG |
| Solvent | DPG to give a 10% solution of Coumarin |
| Physical state | Liquid |
| Synonyms | 1-benzopyran-2-one |
| Supplier IFRA information | Catalogue copy mentions IFRA information, but no reviewed supplier-document record is available in this profile. No certificate, use limit or compliance status is confirmed. |
| IFRA document scope | Where an IFRA document is shared with the raw material, it refers to the raw, undiluted material. It is supplied as a reference for this diluted product; its stated limits are not limits for the supplied dilution. Check the document scope and assess the intended finished formulation. This notice does not confirm that a document is available. |
Safety & handling
Contains: Coumarin
Hazard statements:
- H302 Harmful if swallowed.
- H317 May cause an allergic skin reaction.
- H412 Harmful to aquatic life with long lasting effects.
Precautionary statements:
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray
- P264 Wash thoroughly after handling
- P270 Do not eat, drink or smoke when using this product
- P272 Contaminated work clothing should not be allowed out of the workplace
- P273 Avoid release to the environment
- P280 Wear protective gloves/protective clothing/eye protection/face protection
- P301+312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell
- P302+352 IF ON SKIN: Wash with soap and water
- P330 Rinse mouth
- P333+313 If skin irritation or a rash occurs: Get medical advice/attention
- P363 Wash contaminated clothing before reuse
- P501 Dispose of contents/container in accordance with local regulations
Professional/Industrial use only.
Datasheets & customer documents
Available documents are attached to eligible completed orders in your account.
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Supplementary documents are supplied only where explicitly listed and available. Check documentation information
Purchased as a guest? Follow the SDS request guidance in our Documentation Supply Policy and provide proof of purchase.
Documentation Supply PolicyIFRA formulation guide
Generic reference only — not an IFRA certificate, compliance decision or use recommendation. The Responsible Person and qualified safety assessor must assess the actual finished formula using current applicable IFRA Standards, supplementary documentation where available and the CPSR.
Raw undiluted material reference. These data refer to the named active material, not the complete supplied dilution. A raw-material IFRA ceiling is not a use level for this diluted product. The assessor must account for the actual concentration, carrier and all other formula contributions.
Source: 51st Amendment overview, held source checked 2026-10-21. Bundle 2026-10-27. Individual Standards prevail over the overview.
Coumarin
RESTRICTION · CAS 91-64-5
Category 4 — fine fragrance: 1.5% in the finished consumer product
All applicable specification, purity and other Standard conditions must also be met.
All IFRA categories and Standard conditions
| Category 1 | 0.089% in the finished consumer product |
|---|---|
| Category 2 | 0.08% in the finished consumer product |
| Category 3 | 0.089% in the finished consumer product |
| Category 4 | 1.5% in the finished consumer product |
| Category 5A | 0.38% in the finished consumer product |
| Category 5B | 0.11% in the finished consumer product |
| Category 5C | 0.16% in the finished consumer product |
| Category 5D | 0.035% in the finished consumer product |
| Category 6 | 0.0024% in the finished consumer product |
| Category 7A | 0.18% in the finished consumer product |
| Category 7B | 0.18% in the finished consumer product |
| Category 8 | 0.035% in the finished consumer product |
| Category 9 | 0.52% in the finished consumer product |
| Category 10A | 0.52% in the finished consumer product |
| Category 10B | 1.6% in the finished consumer product |
| Category 11A | 0.035% in the finished consumer product |
| Category 11B | 0.035% in the finished consumer product |
| Category 12 | 33% in the finished consumer product |
CAS numbers (comment): The scope of this Standard includes, but is not limited to the CAS number(s) indicated above; any other CAS number(s) used to identify this fragrance ingredient should be considered in scope as well.
Contributions from other sources: See Annex
Flavor use consideration: Due to the possible ingestion of small amounts of fragrance ingredients from their use in products in Categories 1 and 6, materials must not only comply with IFRA Standards but must also be recognized as safe as a flavoring ingredient as defined by the IOFI Code of Practice (www.iofi.org). For more details see chapter 1 of the Guidance for the use of IFRA Standards.
IFRA Standard type: RESTRICTION
Intrinsic property driving the risk management measure: DERMAL SENSITIZATION AND SYSTEMIC TOXICITY
Amendment revised: 49
Existing creations deadline: February 10, 2022
New creations deadline: February 10, 2021
IFRA source overview · Individual IFRA Standards and supplementary documentation
Supplier certificates and private documents are separate evidence. Their availability does not determine whether this generic guide is shown. This is a dated local reference, not a live regulatory feed.
Creative ideas to explore
Creative directions, not tested formulas.Sweetness and grain
With sandalwood and dry wood notesExplore a gourmand sketch framed by wood rather than more sweetness. Compare a creamy wood direction with a drier one, deciding whether the material works best as the centre of the idea or as a softer background.
Citrus confection
With bergamot and a peel directionTry a contrast between the gourmand character and a citrus opening. Compare a peel-led version with a sweeter reference, looking for a balance that evokes your intended confection without turning every part of the composition sweet.
Petal cream
With rose and a soft floral accordSet the gourmand material beside a familiar flower for a petal-and-cream concept. Evaluate the floral reference and the sweeter variation together, then choose whether the result should remain recognisably floral or move towards a dessert impression.







Elias (verified owner) –
Fantastic tonka
Somer S. (verified owner) –
It does exactly what it’s says on the tin 🤘
Ola S. (verified owner) –
Good
Franca Tulino (verified owner) –
Antonio Turiello (verified owner) –
Coumarin, the easiest way to boost your sweet tonka like fragrance, can be truly used with vanilla and woody stuff to blend a very solid bottom notes.Intoxicating blend with coconut water , sandal, benzoin, jasmine and oranger.